metal-free electrochemical fluorodecarboxylation of

Emerging chemical risks in Europe — 'PFAS'

It is currently not possible to perform in-depth environmental and health risk assessments of all chemical substances in use in Europe because of the great variety of chemicals and their diverse uses. New and legacy chemicals continue to be released into Europe's environment, adding to the total chemical burden on Europe's citizens and ecosystems. Early identification of emerging risks is

Fluorinated Heterocyclic Compounds: Synthesis,

Other reagents found capable of oxidizing highly fluorinated imines were chlorine gas in the presence of a metal carbonate,182 50% hydrogen peroxide,183 CF3OOC(O)F, and CF2(OF)2.184 All, including CF3OOH, are highly reactive oxidizers and most pose an

Lead Elimination

A transition metal-free decarboxylative fluorination of cinnamic acids with Selectfluor has recently been reported by Tang and coworkers [6]. Functionalized cinnamic acid derivatives react with 2 equiv of Selectfluor and 4 equiv of base in hydrophobic solvents and water to give fluorostyrene with good yield and Z -stereoselectivity.

Developing highly selective and efficient transition-metal-catalyzed C-C, and C-heteroatom bond formation in syntheses, e.g. oxidative coupling reactions, C-H bond functionalization Small molecule (such as CO, O 2, N 2 O, H 2 O 2, NH 3, ClO 2, etc.) activation with an emphasis on applying such molecules in efficient synthetic methods

Radical Decarboxylative Fluorination of Aryloxyacetic Acids

R. Waldvogel, Metal-free electrochemical fluorodecarboxylation of aryloxyacetic acids to fluoromethyl aryl ethers Lionel Remisse, Damien Jardel, Dominique Lastcoures, Jean-Marc Vincent, Light-promoted metal-free cross dehydrogenative 53,

Asian Journal of Organic Chemistry: Vol 9, No 11

2020/9/11A metal‐free simple and straightforward KI‐catalyzed approach has been established towards the construction of pyrazole linked benzothiazoles by using inexpensive and odorless elemental sulfur. These pyrazole‐benzothiazole hybrid derivatives exhibited excellent photophysical properties with quantum yield (Φ F ) up to 66%.

Molecules

The oxidation of primary alcohols under mechanochemical conditions in a Spex8000M Mixer/Mill was investigated. To facilitate ease of separation and recyclability, a polystyrene-bound version of a TEMPO catalyst was employed. When paired with Oxone in a stainless-steel vial with a stainless-steel ball, several primary alcohols were successfully oxidized to the corresponding carboxylic acids.

Emerging chemical risks in Europe — 'PFAS'

It is currently not possible to perform in-depth environmental and health risk assessments of all chemical substances in use in Europe because of the great variety of chemicals and their diverse uses. New and legacy chemicals continue to be released into Europe's environment, adding to the total chemical burden on Europe's citizens and ecosystems. Early identification of emerging risks is

Recent advances in green fluorine chemistry

Recent advances in green fluorine chemistry Yuwen Zeng, Jinbo HuKey Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai, Peoplersquo;s Republic of ChinaAbstract: Fluorinated compounds are intriguing for the development of pharmaceuticals, agrochemicals, and materials, and thus, much effort has been exerted to develop

Developing highly selective and efficient transition-metal-catalyzed C-C, and C-heteroatom bond formation in syntheses, e.g. oxidative coupling reactions, C-H bond functionalization Small molecule (such as CO, O 2, N 2 O, H 2 O 2, NH 3, ClO 2, etc.) activation with an emphasis on applying such molecules in efficient synthetic methods

Organometallic Chemistry: Review:Metal–Ligand Cooperation

Metal free 129 Metathesis 24 Mg Catalyzed 10 Michael addition 15 Michael Reaction 13 Mizoroki-Heck Rxn 6 Mn catalyzed 42 Mo Catalyzed 7 Multicomponent reaction 35 Multicomponent Rxn 32 Nanoparticles 13 Natural products 60 Nazarov Cyclization 14 17

Emerging chemical risks in Europe — 'PFAS'

It is currently not possible to perform in-depth environmental and health risk assessments of all chemical substances in use in Europe because of the great variety of chemicals and their diverse uses. New and legacy chemicals continue to be released into Europe's environment, adding to the total chemical burden on Europe's citizens and ecosystems. Early identification of emerging risks is

The Roots of Organic Development (Industrial

Fluorodecarboxylation of 2-phenylphenylchoroformate Finaly 1-fluoronaphthalene can be obtained with a very high yield from c~naphthylchloroformate (entry 12). The influence of reaction temperature was examined in the case of the decarboxylation of meta-tolylchloroformate 6 in 3-fluorotoluene _7.

Electrochemical Synthesis of Fluoromethyl Aryl Ethers ::

However, existing methods for this type of reaction require metal catalysts or an excess of oxidizing and fluorinating agents. Siegfried R. Waldvogel, University of Mainz, Germany, and colleagues have developed a sustainable, metal-free, electrochemical fluorodecarboxylation of aryloxyacetic acids (Ar–O–CH 2 –COOH) to give fluoromethyl aryl ethers.

Radical fluorination methods for the synthesis of aryl

Title Radical fluorination methods for the synthesis of aryl mono-, di-, and tri- fluoromethyl ethers Creator Leung, Joe Cho Tak Publisher University of British Columbia Date Issued 2013 Description New reagents for selective radical fluorine transfer have been identified

Electrochemical Synthesis of Battery Electrode Materials

Electrochemical impedance spectra (EIS) indicated the formation of a resistive film for [BMIm]TFSA, whereas a protective layer was obtained over the Na metal in the case of [BMIm]FSA. However, the EIS spectra did not show much change in the presence of Na ions in the ILs, due to immediate formation of a Na + containing surface film.

Fluorinating Agents in Organic Chemistry

the substrate. Another advantage is that, since free hydrogen fluoride is not a major by-product in fluorination reactions with this type of reagent, conventional glass equipment is often suitable. Scheme 1 The chemistry of N-F fluorinating agents has been reviewed.

Electrochemical synthesis and properties of δ

Read Electrochemical synthesis and properties of δ-fluoroacyl and δ-perfluoroalkyl transition metal complexes, Russian Chemical Bulletin on DeepDyve, the largest online rental service for scholarly research with thousands of academic publications available at

Electronic Supplementary Information

S1 Electronic Supplementary Information Metal-free Electrochemical Fluorodecarboxylation of Aryloxyacetic Acids to Fluoromethyl Aryl Ethers Michael Berger, John D. Herszman, Yuji Kurimoto, Goswinus H. M. de Kruijff, Schll, Sven Ruf, Siegfried R

Metal

Metal-free and base-free decarboxylation of substituted cinnamic acids in a deep eutectic solvent Wen-Bing Sheng TCM and Ethnomedicine Innovation Development International Laboratory, Academician Atta-ur-Rahman Belt and Road Traditional Medicine Research Center, Innovative Materia Medica Research Institute, School of Pharmacy, Hunan University of Chinese Medicine, Changsha,

Fluorinated Heterocyclic Compounds: Synthesis,

Other reagents found capable of oxidizing highly fluorinated imines were chlorine gas in the presence of a metal carbonate,182 50% hydrogen peroxide,183 CF3OOC(O)F, and CF2(OF)2.184 All, including CF3OOH, are highly reactive oxidizers and most pose an

Transition Metal

Transition metals play a vital role in modern synthetic organic chemistry. Transition metal-mediated radical reactions have also been firmly established as an indispensable tool in organic synthesis. However, their importance in C(sp 3)–F bond formations was not realized until Li et al. reported the silver-catalyzed decarboxylative fluorination of aliphatic carboxylic acids in 2012 [].

The Roots of Organic Development (Industrial

Fluorodecarboxylation of 2-phenylphenylchoroformate Finaly 1-fluoronaphthalene can be obtained with a very high yield from c~naphthylchloroformate (entry 12). The influence of reaction temperature was examined in the case of the decarboxylation of meta-tolylchloroformate 6 in 3-fluorotoluene _7.

Molecules

This review article focused on the innovative procedure for electrophilic fluorination using HF and in situ generation of the required electrophilic species derived from hypervalent iodine compounds. The areas of synthetic application of this approach include fluorination of 1,3-dicarbonyl compounds, aryl-alkyl ketones, styrene derivatives, alpha;,beta;-unsaturated ketones and alcohols

Metal

Electrochemical decarboxylation of aryloxyacetic acids followed by fluorination provides easy access to fluoromethyl aryl ethers. This electrochemical fluorodecarboxylation offers a sustainable approach with electric current as traceless oxidant. Using Et 3 N5HF as fluoride source and as supporting electrolyte, this simple electrosynthesis affords various fluoromethoxyarenes in yields up to 85%.

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